The liberty cap is a small, slender mushroom of grassland with a sharply pointed cap, and it is the only psilocybin mushroom that grows wild in Britain in any numbers. A Swiss survey of more than a hundred European species found that it is one of just two psilocybin-containing fungi that occur in Middle and Northern Europe in quantities large enough to be collected (Stijve and Kuyper 1985). That is why it has a common name, a legal history and a long record in poison centre files.
This site explains the species. It is not a guide to finding or picking it. In the United Kingdom any fungus containing psilocin has been a Class A drug since 18 July 2005, and picking a liberty cap to keep it counts as possession. In the Netherlands the species has been named on List II of the Opium Act since 1 December 2008. The details, with the exceptions the law makes, are on the law page.
Why this card leads with the lookalikes
The real danger of the liberty cap is the other small brown mushrooms that grow in the same places. Several of them contain toxins that damage the liver or kidneys, and the first symptoms can appear many hours after eating, when it is already late. In Austria a young man looking for liberty caps ate the deadly webcap instead and lost the function of his kidneys (Franz et al. 1996). The UK's drug information service FRANK puts it plainly: the biggest danger is eating a poisonous mushroom by mistake (FRANK).
The features on this card are how mycologists describe the species. They are a summary for understanding, and they overlap with species that can kill. Separating the liberty cap from its closest relative, Psilocybe pelliculosa, takes a microscope and a measurement of the spores.
How the guide is arranged
Each entry answers one question: how the species is described and why that is not enough, which lookalikes share its grassland, where and when it appears, what is known about its chemistry, what the law says in the UK, the Netherlands and elsewhere, and how a Green Park poisoning in 1799 began its recorded history. Every entry names its sources and the date it was last checked.